| Athlete/Team | Sport - Event | Medal |
| Yuri Chechi | Artistic Gymnastics - Mens Artistic Gymnastics Rings | Bronze |
| Igor Cassina | Artistic Gymnastics - Mens Artistic Gymnastics Horizontal Bar | Gold |
| Roberto Cammarelle | Boxing - Mens Boxing Over 91 Kg | Bronze |
| Emiliano Brembilla, Massimiliano Rosolino, Simone Cercato, Filippo Magnini, | Swimming - Mens Swimming 4 X 200m Freestyle Relay | Bronze |
| Federica Pellegrini | Swimming - Womens Swimming 200m Freestyle | Silver |
| Elisa Blanchi, Fabrizia D'Ottavio, Marinella Falca, Daniela Masseroni, Elisa Santoni, Laura Vernizzi, | Rhythmic Gymnastics - Womens Rhythmic Gymnastics Team | Silver |
| Alessandra Sensini | Sailing - Womens Sailing Mistral | Bronze |
| Valentina Turisini | Shooting - Womens Shooting 50m Rifle 3 Positions | Silver |
| Giovanni Pellielo | Shooting - Mens Shooting Trap | Silver |
| Andrea Benelli | Shooting - Mens Shooting Skeet | Gold |
| Lucia Morico | Judo - Womens Judo 78Kg | Bronze |
| Salvatore Sanzo | Fencing - Mens Fencing Individual Foil | Silver |
| Andrea Cassara | Fencing - Mens Fencing Individual Foil | Bronze |
| Aldo Montano | Fencing - Mens Fencing Individual Sabre | Gold |
| Aldo Montano, Gianpiero Pastore, Luigi Tarantino, | Fencing - Mens Fencing Team Sabre | Silver |
| Valentina Vezzali | Fencing - Womens Fencing Individual Foil | Gold |
| Giovanna Trillini | Fencing - Womens Fencing Individual Foil | Silver |
| Andrea Cassara, Salvatore Sanzo, Simone Vanni, | Fencing - Mens Fencing Team Foil | Gold |
| Nikola Radulovic, Gianluca Basile, Giacomo Galanda, Matteo Soragna, Denis Marconato, Gianmarco Pozzecco, Alex Righetti, Rodolfo Rombaldoni, Massimo Bulleri, Michele Mian, Roberto Chiacig, Luca Garri, | Basketball - Mens Basketball | Silver |
| Paolo Bettini | Cycling - Road - Mens Cycling Road Road Race | Gold |
| Giuseppe Gibilisco | Track & Field - Mens Athletics Pole Vault | Bronze |
| Stefano Baldini | Track & Field - Mens Athletics Marathon | Gold |
| Ivano Brugnetti | Track & Field - Mens Athletics 20Km Road Walk | Gold |
| Andrea Barzagli, Daniele Bonera, Cesare Bovo, Giorgio Chiellini, Daniele de Rossi, Simone del Nero, Marco Donadel, Matteo Ferrari, Andrea Gasbarroni, Alberto Gilardino, Giandomenico Mesto, Emiliano Moretti, Angelo Palombo, Ivan Pelizzoli, Giampiero Pinzi, Andrea Pirlo, Giuseppe Sculli, | Soccer - Mens Football | Bronze |
| Rossano Galtarossa, Alessio Sartori, | Rowing - Mens Rowing Double Sculls | Bronze |
| Lorenzo Porzio, Dario Dentale, Luca Agamennoni, Raffaello Leonardo, | Rowing - Mens Rowing Four | Bronze |
| Lorenzo Bertini, Catello Amarante, Salvatore Amitrano, Bruno Mascarenhas, | Rowing - Mens Rowing Lightweight Four | Bronze |
| Josefa Idem | Canoe/Kayak Flatwater - Womens Canoeing Flat Water K-1 500m | Silver |
| Antonio Rossi, Beniamino Bonomi, | Canoe/Kayak Flatwater - Mens Canoeing Flat Water K-2 1000m | Silver |
